⚛️ Chemistry · Chemical Reactions

Memory tricks for VSEPR, polarity & intermolecular forces

From the five reaction types to balancing equations to Le Chatelier's principle — these memory tricks lock in the rules for predicting how, and how fast, a chemical reaction actually proceeds.

Memory Tricks

Proven mnemonics — fast to learn, hard to forget.

⚛️ Chemical Reactions — 9 Memory Tricks  ·  Click any card to expand · Save favorites · Switch to Flashcard or Quiz mode below
Reaction Types
SDSDC (S=Synthesis, D=Decomposition, S=Single replacement, D=Double replacement, C=Combustion)
Synthesis · Decomposition · Single replacement · Double replacement · Combustion
Every reaction in general chemistry fits one of five categories. SDSDC: Synthesis (A+B→AB) · Decomposition (AB→A+B) · Single Replacement (A+BC→AC+B) · Double Replacement (AB+CD→AD+CB) · Combustion (fuel+O₂→CO₂+H₂O). Identify the type first — then predict the products.
📖 Full Lesson → Difficulty: Beginner
Synthesis
Two or more substances combine to form one product. 2H₂ + O₂ → 2H₂O. Always A + B → AB pattern.
Decomposition
One compound breaks into two or more simpler substances. 2H₂O → 2H₂ + O₂. Opposite of synthesis.
Single replacement
One element displaces another from a compound. Zn + CuSO₄ → ZnSO₄ + Cu. Use activity series to predict if it occurs.
Double replacement
Ions of two compounds exchange partners. Often produces a precipitate, gas, or water. AgNO₃ + NaCl → AgCl↓ + NaNO₃.
Combustion
Hydrocarbon + O₂ → CO₂ + H₂O (complete) or CO + H₂O (incomplete). Always exothermic — releases energy.
Redox
OIL RIG
Oxidation Is Loss · Reduction Is Gain (of electrons)
OIL RIG is the most tested mnemonic in all of chemistry. Oxidation Is Loss of electrons — the species being oxidized loses electrons and its oxidation number increases. Reduction Is Gain of electrons — the species being reduced gains electrons and its oxidation number decreases. They always happen together.
📖 Full Lesson → Difficulty: Intermediate
Oxidizing agent
The species that causes oxidation by accepting electrons — it gets REDUCED itself. "OA gets reduced."
Reducing agent
The species that causes reduction by donating electrons — it gets OXIDIZED itself. "RA gets oxidized."
LEO says GER
Alternative: Lose Electrons = Oxidized · Gain Electrons = Reduced. Both mnemonics work — pick your favorite.
Oxidation numbers
Increase = oxidized. Decrease = reduced. Free elements = 0. O usually = -2. H usually = +1. Monatomic ion = its charge.
Balancing
COACH (C=Count atoms, O=Only change Coefficients, A=Atoms conserved, C=Check both sides, H=Hydrogen and oxygen last)
Count atoms · Only change Coefficients · Atoms conserved · Check both sides · Hydrogen and oxygen last
COACH gives you the systematic approach to balancing any equation. Count atoms on each side · Only change Coefficients (never subscripts) · Atoms are Conserved — matter can't be created or destroyed · Check both sides when done · Balance Hydrogen and Oxygen last (they appear in the most compounds).
📖 Full Lesson → Difficulty: Beginner
Never change subscripts
Changing H₂O to H₃O changes the compound entirely. Only the big numbers (coefficients) in front of formulas can change.
Start with metals
Balance elements that appear in only one reactant and one product first. Leave H and O for last — they appear everywhere.
Use fractions if needed
It's fine to use ½ or ¾ as intermediate coefficients — multiply everything by the denominator at the end to clear fractions.
Polyatomic ions
If a polyatomic ion appears unchanged on both sides, balance it as a unit — don't split it into atoms.
Equilibrium
LE CHAT
Le Chatelier's principle — stress the system, it shifts to relieve the stress
LE CHAT: if a system at equilibrium is stressed, it shifts to counteract the stress. Add reactant → shifts right. Remove product → shifts right. Increase pressure → shifts toward fewer moles of gas. Increase temperature → shifts in the endothermic direction. Used to maximize yield in industrial reactions (Haber process).
📖 Full Lesson → Difficulty: Intermediate
Concentration
Add reactant or remove product → shifts right (forward). Remove reactant or add product → shifts left (reverse).
Pressure
Increase pressure (decrease volume) → shifts toward side with fewer moles of gas. Equal moles of gas = no shift.
Temperature
Treat heat as a reactant (endothermic) or product (exothermic). Increase temp → shifts away from heat. Decrease → shifts toward heat.
Catalyst
Speeds up both forward and reverse reactions equally — reaches equilibrium faster but does NOT shift the equilibrium position.
Reaction Rates
CATS (C=Concentration, A=Area/surface area, T=Temperature, S=Surface area catalyst/catalyst)
Concentration · Area (surface) · Temperature · Surface area catalyst
Reaction rate depends on collision frequency and energy. CATS: Concentration (more particles = more collisions) · Area/surface area (powders react faster than chunks) · Temperature (faster molecules = more energetic collisions) · catalyst (lowers activation energy). All four increase the rate of successful collisions.
📖 Full Lesson → Difficulty: Intermediate
Collision theory
Reactions occur when particles collide with sufficient energy (≥ activation energy) and proper orientation. Rate = collision frequency × fraction with enough energy.
Temperature effect
Rule of thumb: every 10°C rise roughly doubles reaction rate. Higher temperature → more molecules exceed activation energy threshold.
Catalyst mechanism
Provides an alternative reaction pathway with lower activation energy. Is regenerated — not consumed. Enzymes are biological catalysts.
Activation energy
Minimum energy needed for a reaction to occur. Shown on energy diagrams as the "hill" between reactants and products. Exothermic: products lower than reactants.
Activity Series
Please Stop Calling Me A Zebra — I Like Copper's Silver Nature
K · Na · Ca · Mg · Al · Zn · Fe · Ni · Sn · Pb · H · Cu · Ag · Au · Pt
The activity series ranks metals by reactivity. Metals higher on the list displace metals lower on it from ionic solutions. Please Stop Calling Me A Zebra — I Like Copper's Silver Nature gives you K→Na→Ca→Mg→Al→Zn→Fe→Ni→Sn→Pb→H→Cu→Ag→Au→Pt from most to least reactive.
📖 Full Lesson → Difficulty: Intermediate
Rule
Metal A displaces Metal B from solution only if A is above B on the activity series. Zn displaces Cu; Cu cannot displace Zn.
Hydrogen's position
Metals above H react with acids to produce H₂ gas. Metals below H (Cu, Ag, Au, Pt) do NOT react with dilute acids.
Most reactive
K, Na, Ca react violently with water producing H₂ gas and metal hydroxide. Never store in water or open air.
Least reactive
Au, Pt are noble metals — resistant to corrosion and most chemical reactions. That's why gold jewelry lasts forever.
Precipitation
SNAP (N=Nitrates always soluble, A=Alkali metals always soluble, P=Perchlorates always soluble — the "S" frames the mnemonic)
Solubility rules: Nitrates Always soluble · Alkali metals Always soluble · Perchlorates Always soluble
SNAP covers the always-soluble categories. Beyond SNAP: most chlorides are soluble EXCEPT AgCl, PbCl₂, Hg₂Cl₂ · most sulfates soluble EXCEPT BaSO₄, PbSO₄, CaSO₄ · most carbonates, phosphates, and hydroxides are INSOLUBLE except with alkali metals or NH₄⁺. Insoluble = precipitate (↓).
📖 Full Lesson → Difficulty: Intermediate
Always soluble
All nitrates (NO₃⁻) · All alkali metal salts (Li⁺, Na⁺, K⁺, Rb⁺, Cs⁺) · All ammonium salts (NH₄⁺) · All perchlorates.
Usually soluble
Chlorides (except Ag⁺, Pb²⁺, Hg₂²⁺) · Sulfates (except Ba²⁺, Pb²⁺, Ca²⁺, Hg₂²⁺) · Acetates.
Usually insoluble
Carbonates · Phosphates · Hydroxides · Sulfides — all insoluble UNLESS combined with alkali metals or NH₄⁺.
Net ionic equation
Remove spectator ions (those that don't participate). The net ionic equation shows only the ions that actually react to form the precipitate.
Exo vs Endo
EXO exits · ENDO enters
Exothermic = heat exits system (ΔH negative) · Endothermic = heat enters system (ΔH positive)
EXO exits — heat leaves the system, surroundings get warm, ΔH is negative. ENDO enters — heat flows into the system from surroundings, surroundings get cold, ΔH is positive. Combustion is always exothermic. Photosynthesis is endothermic. Hand warmers = exo. Ice packs = endo.
📖 Full Lesson → Difficulty: Beginner
ΔH negative
Exothermic — products have LESS energy than reactants. Energy released. Feels hot. Combustion, neutralization, respiration.
ΔH positive
Endothermic — products have MORE energy than reactants. Energy absorbed. Feels cold. Photosynthesis, melting ice, cooking.
Energy diagram
Exothermic: products lower than reactants on the diagram. Endothermic: products higher. Activation energy is the hill in both cases.
Bond energy connection
Breaking bonds requires energy (endothermic). Forming bonds releases energy (exothermic). ΔH = energy to break bonds − energy released forming bonds.
Equilibrium Constant
K = Products over Reactants (raised to their coefficients)
Keq = [products]^coefficients ÷ [reactants]^coefficients
K expression: products in the numerator, reactants in the denominator, each raised to the power of its coefficient. K > 1 → products favored (equilibrium lies to the right). K < 1 → reactants favored (lies left). K = 1 → roughly equal. Pure solids and liquids are NOT included in K expressions.
📖 Full Lesson → Difficulty: Advanced
Writing Keq
For aA + bB ⇌ cC + dD: Keq = [C]^c[D]^d / [A]^a[B]^b. Use molar concentrations for Kc or partial pressures for Kp.
Excluded species
Pure solids (s) and pure liquids (l) have constant concentrations — they're excluded from K expressions. Only aqueous (aq) and gas (g) species are included.
Reaction quotient Q
Q uses same expression as K but with non-equilibrium concentrations. Q < K → reaction proceeds right. Q > K → reaction proceeds left. Q = K → at equilibrium.
Kp vs Kc
Kp uses partial pressures; Kc uses molar concentrations. Related by: Kp = Kc(RT)^Δn where Δn = moles gas products − moles gas reactants.
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🎓 Common Exam Questions
Q: What are the five types of chemical reactions, and how do you recognize each one from its reactants?
A: The five types are Synthesis (A+B→AB, multiple reactants combine into one product), Decomposition (AB→A+B, one compound breaks into multiple products, often needing an energy input), Single Replacement (A+BC→AC+B, a free element displaces another element from a compound — governed by the activity series), Double Replacement (AB+CD→AD+CB, ions of two compounds trade partners, often forming a precipitate, gas, or water), and Combustion (a hydrocarbon fuel reacts with O2 to form CO2 and H2O — O2 as a reactant is the clearest identifying signal).
Q: Explain OIL RIG and why oxidation and reduction always occur together in the same reaction.
A: OIL RIG stands for Oxidation Is Loss (of electrons, oxidation number increases) and Reduction Is Gain (of electrons, oxidation number decreases). They always occur together because electrons lost by the oxidized substance must be gained by some other substance in the same reaction — one cannot happen without the other.
Q: Walk through the COACH method for balancing a chemical equation.
A: COACH: Count the atoms of each element on both sides; Only change Coefficients, never subscripts (since subscripts define a compound's identity); remember Atoms must be Conserved (same count on both sides); Check both sides once finished; balance Hydrogen and Oxygen last, since they tend to appear in the most compounds.
Q: State Le Chatelier's principle and explain how increasing pressure affects a gas-phase equilibrium.
A: Le Chatelier's principle states that a system at equilibrium, when stressed by an external change, shifts in the direction that partially relieves that stress. Increasing pressure (by decreasing volume) shifts a gas-phase equilibrium toward whichever side has fewer total moles of gas, since that side takes up less volume and partially relieves the increased pressure; if gas moles are equal on both sides, pressure has no effect.
Q: What four factors increase reaction rate (CATS), and which one works by a fundamentally different mechanism than the others?
A: CATS: Concentration and surface Area both increase collision frequency; Temperature increases both collision frequency and the fraction of collisions with enough energy to react; a catalyst works differently — it lowers the activation energy itself by providing an alternative reaction pathway, without changing temperature or collision frequency at all.